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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China GB07-7 Knee high waterproof anti slip steel toe red glitter pvc safety rain boots men manufacturer

    GB07-7 Knee high waterproof anti slip steel toe red glitter pvc safety rain boots men

    1. Materials: 100% PVC upper and sole, easily dried polyester lining
    2. Size: 39-46
    3. Average Height: 36-38 cm (Average)
    4. Toe cap & mid sole: steel toe cap & steel mid-sole
    5. Function: Slip/ oil/ acid/ alkali/ chemical/ greese/ impact/ puncture resistant, 100% waterproof
    6. Usage: Construction site, mining, oil industry, garden, agriculture, farming etc.
    7. Package: 1 pair per poly bag, 10 pairs per carton. or as your required.
    8. Order time: 40 days after receiving the deposit

  • China GB07-6 Orange waterproof anti slip shiny pvc safety rain boots with steel toe manufacturer

    GB07-6 Orange waterproof anti slip shiny pvc safety rain boots with steel toe

    1. Materials: 100% PVC upper and sole, easily dried polyester lining
    2. Size: 39-46
    3. Average Height: 36-38 cm (Average)
    4. Toe cap & mid sole: steel toe cap & steel mid-sole
    5. Function: Slip/ oil/ acid/ alkali/ chemical/ greese/ impact/ puncture resistant, 100% waterproof
    6. Usage: Construction site, mining, oil industry, garden, agriculture, farming etc.
    7. Package: 1 pair per poly bag, 10 pairs per carton. or as your required.
    8. Order time: 40 days after receiving the deposit

  • China GB07-5 Waterproof anti slip food industry white shiny pvc safety rain boots manufacturer

    GB07-5 Waterproof anti slip food industry white shiny pvc safety rain boots

    1. Materials: 100% PVC upper and sole, easily dried polyester lining
    2. Size: 39-46
    3. Average Height: 36-38 cm (Average)
    4. Toe cap & mid sole: steel toe cap & steel mid-sole
    5. Function: Slip/ oil/ acid/ alkali/ chemical/ greese/ impact/ puncture resistant, 100% waterproof
    6. Usage: Construction site, mining, oil industry, garden, agriculture, farming etc.
    7. Package: 1 pair per poly bag, 10 pairs per carton. or as your required.
    8. Order time: 40 days after receiving the deposit

  • China HS1030 oil slip resistant steel toe cheap price men safety shoes for industrial manufacturer

    HS1030 oil slip resistant steel toe cheap price men safety shoes for industrial

    1. Materials: Embossed cow leather upper, PU dual density sole, soft air mesh fabric
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM148 cold resistance rubber outsole composite toe winter safety shoes for men manufacturer

    TM148 cold resistance rubber outsole composite toe winter safety shoes for men

    1. Materials: Embossed cow leather upper, PU/ rubber sole, fur lining
    2. Size: 36-46
    3. Toe cap & mid sole: Composite toe cap & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, keep warm, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM261 Black microfiber leather steel toe men safety shoes for construction manufacturer

    TM261 Black microfiber leather steel toe men safety shoes for construction

    1. Materials: Microfiber leather upper, PU single density sole, air mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe cap & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3055 Non-slip microfiber leather anti-smashing light weight fashion safety shoes for men manufacturer

    TM3055 Non-slip microfiber leather anti-smashing light weight fashion safety shoes for men

    1. Materials: Microfiber leather upper, PU single density sole, air mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe cap & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM077B Black 12 inch cow leather steel toe anti puncture welding safety boots men manufacturer

    TM077B Black 12 inch cow leather steel toe anti puncture welding safety boots men

    1. Materials: Embossed cow leather upper, PU dual density sole, air mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe cap & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China 708 Black microfiber leather steel toe labor protection fashion safety shoes for men manufacturer

    708 Black microfiber leather steel toe labor protection fashion safety shoes for men

    1. Materials: Microfiber leather upper, rubber sole, air mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe cap & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3171 Oil Acid resistant TPU sole industrial safety shoes with composite toe manufacturer

    TM3171 Oil Acid resistant TPU sole industrial safety shoes with composite toe

    1. Materials: Embossed cow leather upper, PU/ TPU,  Soft mesh fabric
    2. Size: 36-46
    3. Toe cap & mid sole: Composite toe cap & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ chemical/ petrol/ impact/ puncture resistant, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

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News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!