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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3267 new TPU sole steel toe anti puncture fashion sport safety shoes men manufacturer

    TM3267 new TPU sole steel toe anti puncture fashion sport safety shoes men

    1. Materials: Microfiber leather & fabric upper, ETPU & tpu sole, soft air mesh fabric lining
    2. Size: 39-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, shock absorber
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3266 Anti-smashing puncture proof soft pink safety shoes for women manufacturer

    TM3266 Anti-smashing puncture proof soft pink safety shoes for women

    1. Materials: 3D fly knit fabric upper, EVA sole, soft air mesh fabric lining
    2. Size: 36-39
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, shock absorber
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3269 Anti puncture comfort fashion sport safety shoes with steel toe manufacturer

    TM3269 Anti puncture comfort fashion sport safety shoes with steel toe

    1. Materials: 3D fly knit fabric upper, EVA sole, soft air mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, shock absorber
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM085 composite toe anti puncture 18KV insulation safety shoes for electrician manufacturer

    TM085 composite toe anti puncture 18KV insulation safety shoes for electrician

    1. Materials: Embossed cow leather upper, PU dual density sole, soft air mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Composite toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: 18kv insulation, slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3265 anti-smashing puncture proof sports fashion safety shoes manufacturer

    TM3265 anti-smashing puncture proof sports fashion safety shoes

    1. Materials: 3D fly knit fabric upper, EVA sole, soft air mesh fabric lining
    2. Size: 39-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, shock absorber
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3264 high ankle steel toe puncture proof sneaker safety boot for men manufacturer

    TM3264 high ankle steel toe puncture proof sneaker safety boot for men

    1. Materials: 3D fly knit fabric upper, EVA sole, soft air mesh fabric lining
    2. Size: 39-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, shock absorber
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3263 high ankle steel toe anti puncture men fashion safety sport shoes manufacturer

    TM3263 high ankle steel toe anti puncture men fashion safety sport shoes

    1. Materials: 3D fly knit fabric upper, EVA sole, soft air mesh fabric lining
    2. Size: 35-46
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, shock absorber
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM262 steel toe anti puncture red fashion sport safety shoes for women manufacturer

    TM262 steel toe anti puncture red fashion sport safety shoes for women

    1. Materials: 3D fly knit fabric upper, EVA sole, soft air mesh fabric lining
    2. Size: 35-46
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, shock absorber
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3257 Air cushioned steel toe sport type safety shoes pink for women manufacturer

    TM3257 Air cushioned steel toe sport type safety shoes pink for women

    1. Materials: 3D fly knit fabric upper, PU sole, soft air mesh fabric lining
    2. Size: 35-41
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, breathable, air cushioned
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3240 Oil water resistance steel toe anti puncture safety shoes s3 src manufacturer

    TM3240 Oil water resistance steel toe anti puncture safety shoes s3 src

    1. Materials: Embossed cow leather upper, PU dual density sole, soft air mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

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News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!