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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3409 Anti-slip Spark Protection Genuine Leather Welding Safety Shoes Steel Toe manufacturer

    TM3409 Anti-slip Spark Protection Genuine Leather Welding Safety Shoes Steel Toe

    1. Materials: Embossed full grain leather upper, PU/ rubber sole, soft mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe cap & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3408 HRO Anti-slip Fiberglass Toe Puncture-proof Waterproof Safety Boots High Quality manufacturer

    TM3408 HRO Anti-slip Fiberglass Toe Puncture-proof Waterproof Safety Boots High Quality

    1. Materials: Crazy horse leather upper, PU & rubber sole, soft Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3407 Non-slip Steel Toe Anti-puncture Leather Industrial Safety Boots for Men manufacturer

    TM3407 Non-slip Steel Toe Anti-puncture Leather Industrial Safety Boots for Men

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3405 Anti-slip Steel Toe Puncture-proof Black Leather Work Shoes with Zipper manufacturer

    TM3405 Anti-slip Steel Toe Puncture-proof Black Leather Work Shoes with Zipper

    1. Materials: Embossed split cow leather upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3402 Anti-slip Rubber Sole Suede Leather Steel Toe Safety Shoes Warehouse manufacturer

    TM3402 Anti-slip Rubber Sole Suede Leather Steel Toe Safety Shoes Warehouse

    1. Materials: Suede leather & mesh fabric upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3401 Anti Slip Rubber Sole Steel Toe Puncture-proof Safety Shoes for Men manufacturer

    TM3401 Anti Slip Rubber Sole Steel Toe Puncture-proof Safety Shoes for Men

    1. Materials: PU leather & mesh fabric upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3400 Black Leather Steel Toe Prevent Puncture Safety Boots for Industrial manufacturer

    TM3400 Black Leather Steel Toe Prevent Puncture Safety Boots for Industrial

    1. Materials: Corrected cow leather upper, PU dual density sole, soft Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3399 Waterproof Anti-slip Comfort Lightweight EVA Work Shoes for Kitchen Hospital manufacturer

    TM3399 Waterproof Anti-slip Comfort Lightweight EVA Work Shoes for Kitchen Hospital

    1. Materials: EVA upper, EVA & anti-skid rubber sole
    2. Size: 36-45
    3. Toe cap:  No
    4. Standard: CE EN ISO 20345:2022 OB FO SR or others
    5. Function: Slip/ oil/ chemical resistant, waterproof, comfortable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3398 Non-slip Anti-smashing Steel Toe Construction Safety Shoes Sports manufacturer

    TM3398 Non-slip Anti-smashing Steel Toe Construction Safety Shoes Sports

    1. Materials: Microfiber leather upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3391 Non-slip Anti-smashing Steel Toe Puncture-proof Red Sport Safety Shoes Women manufacturer

    TM3391 Non-slip Anti-smashing Steel Toe Puncture-proof Red Sport Safety Shoes Women

    1. Materials: Fly knit fabric upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

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Cell Phone: +86 13936186368
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News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!