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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3469 Grey Suede Welding Safety Shoes Steel Toe Puncture-proof Rubber Sole manufacturer

    TM3469 Grey Suede Welding Safety Shoes Steel Toe Puncture-proof Rubber Sole

    1. Materials: Suede leather upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3469 Steel Toe Anti-puncture Welding Safety Shoes Suede Leather Non-slip Rubber Sole manufacturer

    TM3469 Steel Toe Anti-puncture Welding Safety Shoes Suede Leather Non-slip Rubber Sole

    1. Materials: Suede leather upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3468 Oil Slip Resistant Rubber Sole Steel Toe Anti-puncture Labor Work Safety Shoes manufacturer

    TM3468 Oil Slip Resistant Rubber Sole Steel Toe Anti-puncture Labor Work Safety Shoes

    1. Materials: Microbier leather & mesh fabric upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3467 Nubuck Leather Fiberglass Toe Anti-puncture High Quality Safety Boots manufacturer

    TM3467 Nubuck Leather Fiberglass Toe Anti-puncture High Quality Safety Boots

    1. Materials: Nubuck leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China GB39 Heavy Duty Waterproof Steel Toe Steel Mid-sole Black PVC Safety Rain Boots with Logo manufacturer

    GB39 Heavy Duty Waterproof Steel Toe Steel Mid-sole Black PVC Safety Rain Boots with Logo

    1. Materials: 100% PVC upper and sole, easily dried polyester lining
    2. Size: 38-47
    3. Height: 36-38 cm
    4. Toe cap & mid sole: steel toe cap & steel mid-sole
    5. Function: Slip/ oil/ acid/ alkali/ chemical/ greese/ impact/ puncture resistant, 100% waterproof
    6. Usage: Construction, mining, industrial, farming, fishing, factory, workshop etc.
    7. Package: 1 pair per poly bag, 10 pairs per carton. or as your required.
    8. Order time: 40 days after receiving the deposit

  • China GB39 High Quality Waterproof Steel Toe Anti-puncture PVC Safety Rain Gumboots Black manufacturer

    GB39 High Quality Waterproof Steel Toe Anti-puncture PVC Safety Rain Gumboots Black

    1. Materials: 100% PVC upper and sole, easily dried polyester lining
    2. Size: 38-47
    3. Height: 36-38 cm
    4. Toe cap & mid sole: steel toe cap & steel mid-sole
    5. Function: Slip/ oil/ acid/ alkali/ chemical/ greese/ impact/ puncture resistant, 100% waterproof
    6. Usage: Construction, mining, industrial, farming, fishing, factory, workshop etc.
    7. Package: 1 pair per poly bag, 10 pairs per carton. or as your required.
    8. Order time: 40 days after receiving the deposit

  • China TM097 Brown Leather EU Steel Toe Puncture-proof Industrial Safety Boots for Men manufacturer

    TM097 Brown Leather EU Steel Toe Puncture-proof Industrial Safety Boots for Men

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3466 Oil Slip Resistant EU Steel Toe Anti-puncture Safety Boots for Men manufacturer

    TM3466 Oil Slip Resistant EU Steel Toe Anti-puncture Safety Boots for Men

    1. Materials: Corrected cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3463 Anti-slip Durable Rubber Sole Steel Toe Suede Safety Shoes for Men manufacturer

    TM3463 Anti-slip Durable Rubber Sole Steel Toe Suede Safety Shoes for Men

    1. Materials: Suede leather upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3451 Steel Toe Anti-puncture Blue Suede Hiking Sport Safety Shoes for Men manufacturer

    TM3451 Steel Toe Anti-puncture Blue Suede Hiking Sport Safety Shoes for Men

    1. Materials: Cow suede leather upper, EVA & Rubber sole, Soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, anti-static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

Contact us

Contact Person: Kevin Wang
Job Title: General Manager
Cell Phone: +86 13936186368
Skype: kevinsafer
Whatsapp: +86 13936186368
Email:wyf1@saferltd.com
News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!