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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3423 Slip Resistant Wide Steel Toe Anti-puncture Breathable Grey Suede Safety Shoes manufacturer

    TM3423 Slip Resistant Wide Steel Toe Anti-puncture Breathable Grey Suede Safety Shoes

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3422 Grey Suede Leather Wide Steel Toe Anti-puncture Warehouse Work Shoes manufacturer

    TM3422 Grey Suede Leather Wide Steel Toe Anti-puncture Warehouse Work Shoes

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3421 Anti-slip Rubber Sole Steel Toe Brown Suede Leather Work Shoes without Laces manufacturer

    TM3421 Anti-slip Rubber Sole Steel Toe Brown Suede Leather Work Shoes without Laces

    1. Materials: Suede leather upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3420 Oil Slip Resistant Rubber Sole Steel Toe Anti-puncture Suede Work Safety Shoes manufacturer

    TM3420 Oil Slip Resistant Rubber Sole Steel Toe Anti-puncture Suede Work Safety Shoes

    1. Materials: Suede leather upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3419 Non-slip Steel Toe Anti-puncture Breathable Suede Safety Shoes Warehouse manufacturer

    TM3419 Non-slip Steel Toe Anti-puncture Breathable Suede Safety Shoes Warehouse

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3418 Oil Slip Resistant Steel Toe Puncture-proof Suede Work Shoes Low Cut manufacturer

    TM3418 Oil Slip Resistant Steel Toe Puncture-proof Suede Work Shoes Low Cut

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 38-46
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3417 Non-slip Black Leather Steel Toe Anti-puncture Men Construction Safety Boots manufacturer

    TM3417 Non-slip Black Leather Steel Toe Anti-puncture Men Construction Safety Boots

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3415 Grey Anti-slip Steel Toe Puncture-proof Comfort Safety Shoes Sport Design manufacturer

    TM3415 Grey Anti-slip Steel Toe Puncture-proof Comfort Safety Shoes Sport Design

    1. Materials: Microfiber leather upper, Soft EVA sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3413 Anti-slip Steel Toe Puncture-proof Fashion Sport Safety Shoes Lightweight manufacturer

    TM3413 Anti-slip Steel Toe Puncture-proof Fashion Sport Safety Shoes Lightweight

    1. Materials: Microfiber leather upper, Soft EVA sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3412 EU Steel Toe Anti-puncture Black Leather Industrial Safety Boots for Men manufacturer

    TM3412 EU Steel Toe Anti-puncture Black Leather Industrial Safety Boots for Men

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

Contact us

Contact Person: Kevin Wang
Job Title: General Manager
Cell Phone: +86 13936186368
Skype: kevinsafer
Whatsapp: +86 13936186368
Email:wyf1@saferltd.com
News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!