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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3436 Anti-slip Steel Toe Puncture-proof Red Sport Safety Shoes for Women manufacturer

    TM3436 Anti-slip Steel Toe Puncture-proof Red Sport Safety Shoes for Women

    1. Materials: Fly knit fabric upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3433 Slip Resistant Steel Toe Anti-puncture Black Suede Safety Shoes Men manufacturer

    TM3433 Slip Resistant Steel Toe Anti-puncture Black Suede Safety Shoes Men

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3432 Non-slip Suede Leather Steel Toe Anti-puncture Jogger Safety Shoes manufacturer

    TM3432 Non-slip Suede Leather Steel Toe Anti-puncture Jogger Safety Shoes

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3431 Nubuck Leather Fiberglass Toe High Quality Safety Boots PU Rubber Sole manufacturer

    TM3431 Nubuck Leather Fiberglass Toe High Quality Safety Boots PU Rubber Sole

    1. Materials: Nubuck leather upper, PU & rubber sole, soft Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3430 Full Grain Leather Steel Toe Anti-puncture Construction Safety Boots High Quality manufacturer

    TM3430 Full Grain Leather Steel Toe Anti-puncture Construction Safety Boots High Quality

    1. Materials: Embossed full grain leather upper, PU sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3429 Microfiber Leather Anti-slip Steel Toe Industrial Safety Shoes Cheap manufacturer

    TM3429 Microfiber Leather Anti-slip Steel Toe Industrial Safety Shoes Cheap

    1. Materials: Microfiber leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3428 Black Leather Steel Toe Anti-puncture Construction Work Shoes for Men manufacturer

    TM3428 Black Leather Steel Toe Anti-puncture Construction Work Shoes for Men

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3425 Black Leather Wide Steel Toe Anti-puncture Construction Safety Footwear manufacturer

    TM3425 Black Leather Wide Steel Toe Anti-puncture Construction Safety Footwear

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3423 Slip Resistant Wide Steel Toe Anti-puncture Breathable Grey Suede Safety Shoes manufacturer

    TM3423 Slip Resistant Wide Steel Toe Anti-puncture Breathable Grey Suede Safety Shoes

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3422 Grey Suede Leather Wide Steel Toe Anti-puncture Warehouse Work Shoes manufacturer

    TM3422 Grey Suede Leather Wide Steel Toe Anti-puncture Warehouse Work Shoes

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

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Cell Phone: +86 13936186368
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News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!