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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3061 Air Cushion Anti-slip EU Steel Toe Sneaker Safety Shoes for Men manufacturer

    TM3061 Air Cushion Anti-slip EU Steel Toe Sneaker Safety Shoes for Men

    1. Materials: Fly knit fabric upper,  PU sole, soft mesh fabric lining
    2. Size: 37-46
    3. Toe cap & mid sole: Steel toe cap & aramid fiber mid sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3383 Non-slip Fiberglass Toe Anti-puncture ESD Sport Safety Shoes for Workshop manufacturer

    TM3383 Non-slip Fiberglass Toe Anti-puncture ESD Sport Safety Shoes for Workshop

    1. Materials: Microfiber leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 35-48
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: ESD, slip/ oil/ petrol/ impact/ puncture resistant, metal free, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3382 Non-slip Anti-puncture Fiberglass Toe Leather Safety Boots for Construction manufacturer

    TM3382 Non-slip Anti-puncture Fiberglass Toe Leather Safety Boots for Construction

    1. Materials: Embossed cow leather upper, PU dual density sole, soft Mesh fabric lining
    2. Size: 37-45
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM102 Anti-slip Steel Toe Puncture-proof Green Suede Leather Safety Shoes for Men manufacturer

    TM102 Anti-slip Steel Toe Puncture-proof Green Suede Leather Safety Shoes for Men

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 38-46
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM179 Brown Genuine Leather High Quality Safety Boots with Steel Toe for Industrial manufacturer

    TM179 Brown Genuine Leather High Quality Safety Boots with Steel Toe for Industrial

    1. Materials: Genuine leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM008 EU Fiberglass Toe Puncture-proof Black Leather Safety Boots for Industrial manufacturer

    TM008 EU Fiberglass Toe Puncture-proof Black Leather Safety Boots for Industrial

    1. Materials: Embossed cow leather upper, PU dual density sole, soft Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3381 Anti-slip Fiberglass Toe Puncture-proof Hiking Safety Shoes EVA Rubber Sole manufacturer

    TM3381 Anti-slip Fiberglass Toe Puncture-proof Hiking Safety Shoes EVA Rubber Sole

    1. Materials: Suede leather upper, EVA & rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, metal free, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3380 Anti Slip Steel Toe Puncture Proof Spark Protection Welding Safety Shoes Leather manufacturer

    TM3380 Anti Slip Steel Toe Puncture Proof Spark Protection Welding Safety Shoes Leather

    1. Materials: Embossed cow leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe cap & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3201 EU Steel Toe Anti-puncture Soft Lightweight Sport Safety Shoes for Warehouse manufacturer

    TM3201 EU Steel Toe Anti-puncture Soft Lightweight Sport Safety Shoes for Warehouse

    1. Materials: Fly knit fabric upper,  EVA sole, soft mesh fabric lining
    2. Size: 37-46
    3. Toe cap & mid sole: Steel toe cap & aramid fiber mid sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM059-1 CE & ASTM Electrical 18kv Insulation Fiberglass Toe Safety Shoes Black Leather manufacturer

    TM059-1 CE & ASTM Electrical 18kv Insulation Fiberglass Toe Safety Shoes Black Leather

    1. Materials: Embossed cow leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: 18kv insulation, slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

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Cell Phone: +86 13936186368
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News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!