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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3511 Non-slip EVA Sole Steel Toe Anti-puncture Anti-static Comfort Work Safety Shoes manufacturer

    TM3511 Non-slip EVA Sole Steel Toe Anti-puncture Anti-static Comfort Work Safety Shoes

    1. Materials: Microfiber leather upper, EVA sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti-static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3510 Anti-slip Steel Toe Puncture-proof Black Safety Boots for Construction manufacturer

    TM3510 Anti-slip Steel Toe Puncture-proof Black Safety Boots for Construction

    1. Materials: Microfiber leather upper, EVA sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti-static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3508 Anti-slip EVA & Rubber Sole Steel Toe Anti-puncture Hiking Sport Safety Shoes manufacturer

    TM3508 Anti-slip EVA & Rubber Sole Steel Toe Anti-puncture Hiking Sport Safety Shoes

    1. Materials: Suede leather upper, EVA & rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3507 Twist Lock Steel Toe Anti-puncture Fashion Sports Safety Shoes Lightweight manufacturer

    TM3507 Twist Lock Steel Toe Anti-puncture Fashion Sports Safety Shoes Lightweight

    1. Materials: Microfiber leather upper, EVA sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3506 Slip Resistant Steel Toe Puncture-proof Black Work Safety Shoes for Men manufacturer

    TM3506 Slip Resistant Steel Toe Puncture-proof Black Work Safety Shoes for Men

    1. Materials: mesh fabric with TPU upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3505 HRO Non-slip Rubber Sole Steel Toe Lace-free Welding Safety Boots manufacturer

    TM3505 HRO Non-slip Rubber Sole Steel Toe Lace-free Welding Safety Boots

    1. Materials: Corrected cow leather upper, PU & rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3503 HRO Oil & Acid Resistant Rubber Sole Steel Toe High Quality Safety Boots manufacturer

    TM3503 HRO Oil & Acid Resistant Rubber Sole Steel Toe High Quality Safety Boots

    1. Materials: Genuine leather upper, PU & rubber sole, soft Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3502 Non-slip Anti-smash Puncture-proof Steel Industry Leather Welding Safety Shoes manufacturer

    TM3502 Non-slip Anti-smash Puncture-proof Steel Industry Leather Welding Safety Shoes

    1. Materials: Embossed cow leather upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3501 Steel Toe Puncture-proof Outdoor Hiking Safety Shoes EVA & Rubber Sole manufacturer

    TM3501 Steel Toe Puncture-proof Outdoor Hiking Safety Shoes EVA & Rubber Sole

    1. Materials: Microfiber leather upper, EVA & rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3500 Oil Slip Resistant Steel Toe Steel Mid-sole Leather Safety Boots Construction manufacturer

    TM3500 Oil Slip Resistant Steel Toe Steel Mid-sole Leather Safety Boots Construction

    1. Materials: Embossed genuine leather upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

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Contact Person: Kevin Wang
Job Title: General Manager
Cell Phone: +86 13936186368
Skype: kevinsafer
Whatsapp: +86 13936186368
Email:wyf1@saferltd.com
News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!