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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3450 Non-slip Durable Rubber Sole EU Steel Toe Anti-puncture Suede Safety Shoes manufacturer

    TM3450 Non-slip Durable Rubber Sole EU Steel Toe Anti-puncture Suede Safety Shoes

    1. Materials: Cow suede leather upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3449 Black Leather EU Steel Toe Anti-puncture Men's Construction Work Shoes manufacturer

    TM3449 Black Leather EU Steel Toe Anti-puncture Men's Construction Work Shoes

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3448 Non-slip Rubber Sole Steel Toe Puncture-proof Men's Safety Shoes Breathable manufacturer

    TM3448 Non-slip Rubber Sole Steel Toe Puncture-proof Men's Safety Shoes Breathable

    1. Materials: Microfiber leather & mesh fabric upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3442 Steel Toe Anti-puncture EVA Rubber Sole Brown Suede Safety Shoes for Man manufacturer

    TM3442 Steel Toe Anti-puncture EVA Rubber Sole Brown Suede Safety Shoes for Man

    1. Materials: Cow suede leather upper, EVA & Rubber sole, Soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, anti-static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3439 Non-slip Wide Steel Toe Anti-puncture Leather Winter Safety Boots for Men manufacturer

    TM3439 Non-slip Wide Steel Toe Anti-puncture Leather Winter Safety Boots for Men

    1. Materials: Embossed cow leather upper, PU dual density sole, Artificial wool lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti-cold, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3438 Fiberglass Toe Anti-puncture High Quality Work Boots PU Rubber Sole manufacturer

    TM3438 Fiberglass Toe Anti-puncture High Quality Work Boots PU Rubber Sole

    1. Materials: Nubuck leather upper, PU & rubber sole, soft Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3437 Oil Slip Resistant Wide Steel Toe Anti-puncture Industrial Safety Footwear manufacturer

    TM3437 Oil Slip Resistant Wide Steel Toe Anti-puncture Industrial Safety Footwear

    1. Materials: Embossed cow leather upper, PU dual density sole, Mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3436 Anti-slip Steel Toe Puncture-proof Red Sport Safety Shoes for Women manufacturer

    TM3436 Anti-slip Steel Toe Puncture-proof Red Sport Safety Shoes for Women

    1. Materials: Fly knit fabric upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3433 Slip Resistant Steel Toe Anti-puncture Black Suede Safety Shoes Men manufacturer

    TM3433 Slip Resistant Steel Toe Anti-puncture Black Suede Safety Shoes Men

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3432 Non-slip Suede Leather Steel Toe Anti-puncture Jogger Safety Shoes manufacturer

    TM3432 Non-slip Suede Leather Steel Toe Anti-puncture Jogger Safety Shoes

    1. Materials: Suede leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

Contact us

Contact Person: Kevin Wang
Job Title: General Manager
Cell Phone: +86 13936186368
Skype: kevinsafer
Whatsapp: +86 13936186368
Email:wyf1@saferltd.com
News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!