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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM3497 Black Leather Steel Toe Puncture-proof Construction Safety Boots Non-slip manufacturer

    TM3497 Black Leather Steel Toe Puncture-proof Construction Safety Boots Non-slip

    1. Materials: Embossed cow leather upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3496 Black Suede Leather Steel Toe Anti-puncture Warehouse Safety Shoes manufacturer

    TM3496 Black Suede Leather Steel Toe Anti-puncture Warehouse Safety Shoes

    1. Materials: Suede leather upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM088T Anti-slip Oil Resistant TPU Sole Steel Toe Anti-puncture Safety Shoes Men manufacturer

    TM088T Anti-slip Oil Resistant TPU Sole Steel Toe Anti-puncture Safety Shoes Men

    1. Materials: Embossed cow leather upper, PU & TPU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3489 Men's Fashion Sneakers Safety Shoes Steel Toe Anti-puncture Non-slip PU Sole manufacturer

    TM3489 Men's Fashion Sneakers Safety Shoes Steel Toe Anti-puncture Non-slip PU Sole

    1. Materials: 3D Knitted fabric upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3488 Black Sports Safety Shoes Steel Toe Anti-puncture Non-slip Rubber Sole manufacturer

    TM3488 Black Sports Safety Shoes Steel Toe Anti-puncture Non-slip Rubber Sole

    1. Materials: 3D knitted fabricupper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3487 Cold-proof Winter Safety Boots Steel Toe Puncture-proof Anti-slip for Construction manufacturer

    TM3487 Cold-proof Winter Safety Boots Steel Toe Puncture-proof Anti-slip for Construction

    1. Materials: Microfiber leather upper, PU dual density sole, Artificial wool lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti-cold, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3486 Non-slip Steel Toe Anti-puncture Pink Women Safety Shoes Breathable manufacturer

    TM3486 Non-slip Steel Toe Anti-puncture Pink Women Safety Shoes Breathable

    1. Materials: Microbier leather & fabric upper, rubber sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber midsole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ impact/ puncture resistant, anti static, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3485 Non-slip Steel Toe Puncture-proof Leather Construction Work Shoes for Men manufacturer

    TM3485 Non-slip Steel Toe Puncture-proof Leather Construction Work Shoes for Men

    1. Materials: corrected cow leather upper, PU dual density sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3482 Anti-slip Steel Toe Puncture-proof Sports Work Safety Shoes Breathable manufacturer

    TM3482 Anti-slip Steel Toe Puncture-proof Sports Work Safety Shoes Breathable

    1. Materials: Knitted fabric upper, PU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P FO SR or others
    5. Function: Slip/ oil/ acid/ petrol/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM196 Anti-slip TPU Sole Steel Toe Anti-puncture Safety Boots High Quality manufacturer

    TM196 Anti-slip TPU Sole Steel Toe Anti-puncture Safety Boots High Quality

    1. Materials: Crazy horse leather upper, PU & TPU sole, soft mesh fabric lining
    2. Size: 36-47
    3. Toe cap & mid sole: Steel toe & steel mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

Contact us

Contact Person: Kevin Wang
Job Title: General Manager
Cell Phone: +86 13936186368
Skype: kevinsafer
Whatsapp: +86 13936186368
Email:wyf1@saferltd.com
News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!